a, \(n_{Na}=\dfrac{3,45}{23}=0,15\left(mol\right)\)
\(n_{H_2O}=\dfrac{162}{18}=9\left(mol\right)\)
PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)
Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{9}{2}\) ta được H2O dư.
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{Na}=0,075\left(mol\right)\Rightarrow V_{H_2}=0,075.22,4=1,68\left(l\right)\)
b, \(n_{NaOH}=n_{Na}=0,15\left(mol\right)\)
Ta có: m dd sau pư = 3,45 + 162 - 0,075.2 = 165,3 (g)
\(\Rightarrow C\%_{NaOH}=\dfrac{0,15.40}{165,3}.100\%\approx3,63\%\)