\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(R+2HCl\rightarrow RCl_2+H_2\)
\(0.1........0.2................0.1\)
\(M_R=\dfrac{13.7}{0.1}=137\left(\dfrac{g}{mol}\right)\)
\(R:Ba\)
\(200\left(ml\right)=0.2\left(l\right)\)
\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)