- Trong 3,31 (g) X: 27nAl + 56nFe + 64nCu = 3,31 (1)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{0,86765}{24,79}=0,035\left(mol\right)\left(2\right)\)
- Trong 0,12 mol X có: a.nAl + a.nFe + a.nCu = 0,12 (3)
PT: \(2Al+3Cl_2\underrightarrow{t^O}2AlCl_3\)
____a.nAl__________a.nAl (mol)
\(2Fe+3Cl_2\underrightarrow{t^o}2FeCl_3\)
a.nFe___________a.nFe (mol)
\(Cu+Cl_2\underrightarrow{t^o}CuCl_2\)
a.nCu _________a.nCu (mol)
⇒ 133,5a.nAl + 162,5a.nFe + 135a.nCu = 17,27 (4)
Từ (3) và (4) ⇒ 1,25nAl - 2,23nFe + 1,07nCu = 0 (5)
Từ (1), (2) và (5) \(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,01\left(mol\right)\\n_{Fe}=0,02\left(mol\right)\\n_{Cu}=0,03\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,01.27}{3,31}.100\%\approx8,2\%\\\%m_{Fe}=\dfrac{0,02.56}{3,31}.100\%\approx33,8\\\%m_{Cu}\approx58\%\end{matrix}\right.\)