PTHH: \(Na_2CO_3+Ca\left(OH\right)_2\rightarrow2NaOH+CaCO_3\downarrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Na_2CO_3}=0,1\cdot1=0,1\left(mol\right)\\n_{Ca\left(OH\right)_2}=0,1\cdot1,5=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Ca(OH)2 dư
\(\Rightarrow\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{CaCO_3}=0,1\left(mol\right)\\n_{Ca\left(OH\right)_2\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaCO_3}=0,1\cdot100=10\left(g\right)\\C_{M_{NaOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\\C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\end{matrix}\right.\)
nNa2CO3= 0,1(mol) ; nCa(OH)2=0,15(mol)
a) PTHH: Na2CO3 + Ca(OH)2 -> CaCO3 + 2 NaOH
Vì: 0,1/1 < 0,15/1
=> Na2CO3 hết, Ca(OH)2 dư, tính theo Na2CO3.
=> nCaCO3=nCa(OH)2 (p.ứ)=nNa2CO3= 0,1(mol)
=>m(kết tủa)=mCaCO3=0,1.100=10(g)
b) Vddsau= 100+100=200(ml)=0,2(l)
nNaOH=2.0,1=0,2(mol)
nCa(OH)2(dư)=0,15-0,1=0,05(mol)
=>CMddNaOH=0,2/0,2= 1(M)
CMddCa(OH)2 (dư)= 0,05/ 0,2=0,25(M)