Bài 31:
Gọi số mol KHCO3, CaCO3 là x, y (mol)
\(n_{BaCO_3}=\dfrac{1,97}{197}=0,01\left(mol\right)\)
PTHH: KHCO3 + HCl --> KCl + CO2 + H2O
x----------------------->x
CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
y----------------------------->y
Ba(OH)2 + CO2 --> BaCO3 + H2O
0,01<---0,01
=> x + y = 0,01
a = 100x + 100y = 1 (g)
Bài 32:
Gọi số mol K2CO3, CaCO3 là a, b (mol)
=> 138a + 100b = 11,9 (1)
PTHH: K2CO3 + 2HCl --> 2KCl + CO2 + H2O
a--------------->2a------>a
CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
b-------------->b-------->b
=> \(a+b=\dfrac{2,24}{22,4}=0,1\) (2)
=> a = 0,05; b = 0,05
=> \(\left\{{}\begin{matrix}m_{KCl}=0,1.74,5=7,45\left(g\right)\\m_{CaCl_2}=0,05.111=5,55\left(g\right)\end{matrix}\right.\)
=> mmuối = 7,45 + 5,55 = 13 (g)