a)
2Al + 6H2SO4 --> Al2(SO4)3 + 3SO2 + 6H2O
Zn + 2H2SO4 --> ZnSO4 + SO2 + 2H2O
b)
Gọi số mol Al, Zn là a, b (mol)
=> 27a + 65b = 5,35 (1)
PTHH: 2Al + 6H2SO4 --> Al2(SO4)3 + 3SO2 + 6H2O
a---->3a------------------->1,5a
Zn + 2H2SO4 --> ZnSO4 + SO2 + 2H2O
b----->2b----------------->b
=> \(1,5a+b=\dfrac{5,488}{22,4}=0,245\left(2\right)\)
(1)(2) => a = 0,15 (mol); b = 0,02 (mol)
=> \(\left\{{}\begin{matrix}m_{Al}=0,15.27=4,05\left(g\right)\\m_{Zn}=0,02.65=1,3\left(g\right)\end{matrix}\right.\)
nH2SO4 = 3a + 2b = 0,49 (mol)
=> \(m=\dfrac{0,49.98}{98\%}=49\left(g\right)\)