\(n_A=1\left(mol\right)\)
\(n_{HCl}=a\left(mol\right)\Rightarrow n_{O_2}=1-a\left(mol\right)\)
\(\overline{M}=8.45\cdot4=33.8\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow m=36.5a+32\cdot\left(1-a\right)=33.8\left(g\right)\)
\(\Rightarrow a=0.4\)
\(\%V_{HCl}=\dfrac{0.4}{1}\cdot100\%=40\%\)
\(\%V_{O_2}=60\%\)
\(b.\)
\(n_{HCl}:n_{O_2}=0.4:0.6=2:3\)
\(n_{HCl}=2x\left(mol\right),n_{O_2}=3x\left(mol\right)\)
\(m_{hh}=2x\cdot36.5+3x\cdot32=4.225\left(g\right)\)
\(\Leftrightarrow x=0.025\left(mol\right)\)
\(m_{HCl}=0.025\cdot2\cdot36.5=1.825\left(g\right)\)
\(m_{O_2}=2.4\left(g\right)\)