\(3Cu+8H^++2NO_3^-\rightarrow2NO+4H_2O+3Cu^{2+}\)
3z---->8z----->2z
\(2H^++O^{2-}\rightarrow H_2O\)
2y<---y
\(Cu+2Fe^{3+}\rightarrow Cu^{2+}+2Fe^{2+}\)
x---->2x
+ Hỗn hợp ban đầu: \(\left\{{}\begin{matrix}Fe^{3+}:2x\\O:y\\Cu:x+3z\\NO_3:2z\end{matrix}\right.\)
\(\Sigma n_{Fe}=2x=\dfrac{2z}{3}+\dfrac{2y}{3}\Leftrightarrow3x=y+z\left(1\right)\)
\(\Sigma n_{H^+\left(H_2SO_4\right)}=2y+8z=0,42.2=0,84\left(2\right)\)
\(m=37,06=56.2x+16y+64\left(x+3z\right)+62.2z\left(3\right)\)
Từ (1), (2), (3), giải được \(\left\{{}\begin{matrix}x=0,065\\y=0,12\\z=0,075\end{matrix}\right.\)
Số mol mỗi chất trong X: \(\left\{{}\begin{matrix}n_{Fe\left(NO_3\right)_3}=\dfrac{2z}{3}=\dfrac{2.0,075}{3}=0,05\left(mol\right)\\n_{Fe_2O_3}=\dfrac{y}{3}=\dfrac{0,12}{3}=0,04\left(mol\right)\\n_{Cu}=x+3z=0,065+3.0,075=0,29\left(mol\right)\end{matrix}\right.\)
