\(a.Na+HCl->NaCl+\dfrac{1}{2}H_2\\ Na+H_2O->NaOH+\dfrac{1}{2}H_2\\ 2Al+2NaOH+6H_2O->2Na\left[Al\left(OH\right)_4\right]+3H_2\\ b.\)
Cho Al dư vào X thấy thoát khí nên X có NaOH, HCl hết.
\(n_{H_2}=x\left(mol\right)\\ x=\dfrac{1}{2}n_{HCl}+\dfrac{1}{2}n_{NaOH}=0,05+\dfrac{1}{2}n_{NaOH}\\ Mà:n_{NaOH}=n_{Al}=\dfrac{2}{3}n_{H_2\left(2\right)}=\dfrac{2}{3}x\\ x=0,05+\dfrac{1}{3}x\\ x=0,075\\ a=0,075.23.2=3,45g\)
\(a)2Na+2HCl\xrightarrow[]{}2NaCl+H_2\\ Al+3NaCl\xrightarrow[]{}AlCl_3+3Na\)
\(b)n_{HCl}=0,1.1=0,1\left(mol\right)\\2 Na+2HCl\xrightarrow[]{}2NaCl+H_2\\ n _{Na}=n_{HCl}=0,1mol\\ m _{Na}=0,1.23=2,3\left(g\right)\)