$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$Zn + 2HCl \to ZnCl_2 + H_2$
$n_{Al} = \dfrac{a}{27} (mol) \Rightarrow n_{H_2} = \dfrac{3}{2}n_{Al} = \dfrac{a}{18}(mol)$
$n_{Zn} = \dfrac{b}{65}(mol) \Rightarrow n_{H_2} = n_{Zn} = \dfrac{b}{65}(mol)$
$\Rightarrow \dfrac{a}{18} = \dfrac{b}{65}$
$\Rightarrow \dfrac{a}{b} = \dfrac{18}{65}$
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