a)
\(n_{HCl}=\dfrac{300.7,3\%}{36,5}=0,6\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
FeCO3 + 2HCl --> FeCl2 + CO2 + H2O
\(n_{khí}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PTHH, nHCl(pư) = 2.nkhí = 0,2 (mol) < 0,6 (mol)
=> HCl dư
Gọi số mol Fe, FeCO3 là a, b (mol)
=> \(\left\{{}\begin{matrix}56a+116b=8,6\\a+b=0,1\end{matrix}\right.\)
=> a = 0,05 (mol); b = 0,05 (mol)
=> \(\left\{{}\begin{matrix}m_{Fe}=0,05.56=2,8\left(g\right)\\m_{FeCO_3}=0,05.116=5,8\left(g\right)\end{matrix}\right.\)
nFeCl2 = 0,1 (mol) => mFeCl2 = 0,1.127 = 12,7 (g)
nHCl(dư) = 0,6 - 0,2 = 0,4 (mol) => mHCl(dư) = 0,4.36,5 = 14,6 (g)
mdd sau pư = 8,6 + 300 - 0,05.2 - 0,05.44 = 306,3 (g)
\(\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{12,7}{306,3}.100\%=4,146\%\\C\%_{HCl\left(dư\right)}=\dfrac{14,6}{306,3}.100\%=4,767\%\end{matrix}\right.\)
b)
\(\overline{M}_X=\dfrac{0,05.2+0,05.44}{0,05+0,05}=23\left(g/mol\right)\)
=> \(d_{X/H_2}=\dfrac{23}{2}=11,5\)
