\(n_{Na_2CO_3}=n_{Na_2CO_3\cdot10H_2O}=\dfrac{57.2}{106+18\cdot10}=0.2\left(mol\right)\)
\(C_{M_{Na_2CO_3}}=\dfrac{0.2}{0.4}=0.5\left(M\right)\)
\(m_{Na_2CO_3}=0.2\cdot106=21.2\left(g\right)\)
\(m_{dd}=400\cdot1.05=420\left(g\right)\)
\(C\%_{Na_2CO_3}=\dfrac{21.2}{420}\cdot100\%=5.04\%\)