\(n_{Al_2O_3}=\dfrac{18,36}{102}=0,18\left(mol\right)\\ n_{Al}=\dfrac{0,81}{27}=0,03\left(mol\right)\\ Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\left(1\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\left(2\right)\\ H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\left(3\right)\\ n_{NaOH}=0,05.4=0,2\left(mol\right)\\ n_{H_2SO_4\left(dư\right)}=\dfrac{0,2}{2}=0,1\left(mol\right)\\ n_{Al_2\left(SO_4\right)_3}=0,18+0,5.0,03=0,195\left(mol\right)\\ m_{ddsau}=m_{hh}+m_{ddH_2SO_4}-m_{H_2}\\ =18,36+0,81+300-0,045.2=319,08\left(g\right)\\ C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{342.0,195}{319,08}.100\approx20,901\%\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,1.98}{319,08}.100\approx3,071\%\)
