\(a,n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ 3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\\ b,n_{Fe_3O_4}=\dfrac{n_{Fe}}{3}=\dfrac{0,3}{3}=0,1\left(mol\right)\\ \Rightarrow m_{Fe_3O_4}=232.0,1=23,2\left(g\right)\\ n_{O_2}=\dfrac{2}{3}.n_{Fe}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\)