a)$n_{O_2} = \dfrac{7,2}{24,79} = 0,29(mol)$
$2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2$
$n_{KClO_3} = \dfrac{2}{3}n_{O_2} = \dfrac{29}{150}(mol)$
$m_{KClO_3} = \dfrac{29}{150}.122,5 = 23,683(gam)$
b) $S + O_2 \xrightarrow{t^o} SO_2$
$V_{SO_2} = V_{O_2} = 7,2(lít)$