n SO2 = 4,48/ 22,4 = 0,2 mol
n KOH = 0,3*1 = 0,3 mol
n SO2 < n KOH --> n KOH dư
SO2 + 2KOH --- K2SO3 + H2O
0,2 < 0,3 0,2
CM K2SO4 = 0,2/0,3 = 0,666 M
\(n_{SO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right);n_{KOH}=0,3.1=0,3\left(mol\right)\)
Ta có: \(T=\dfrac{n_{KOH}}{n_{SO_2}}=\dfrac{0,3}{0,2}=1,5\) ⇒ tạo ra muối K2SO3 và KHSO3
PTHH: SO2 + 2KOH → K2SO3 + H2O
Mol: x 2x x
PTHH: SO2 + KOH → KHSO3
Mol: y 2y y
Ta có: \(\left\{{}\begin{matrix}x+y=0,2\\2x+y=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(C_{M_{ddK_2SO_3}}=\dfrac{0,1}{0,3}=0,333M\)
\(C_{M_{ddKHSO_3}}=\dfrac{0,1}{0,3}=0,333M\)