\(n_{Ba}=\dfrac{6,85}{137}=0,05\left(mol\right)\\ m_{H_2SO_4}=500.1,96\%=9,8\left(g\right)\\ PTHH:Ba+H_2SO_4\rightarrow BaSO_4+H_2\uparrow\\ LTL:0,05< 0,1\Rightarrow H_2SO_4.dư\)
\(n_{BaSO_4}=n_{H_2SO_4\left(pư\right)}=n_{Ba}=n_{H_2}=0,05\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,1-0,05=0,05\left(mol\right)\)
\(V_{dd}=\dfrac{500}{1,15}\approx434\left(ml\right)=0,434\left(l\right)\)
\(C_{MBaSO_4}=\dfrac{0,05}{0,434}=0,115M\\ C_{MH_2SO_4\left(dư\right)}=\dfrac{0,05}{0,434}=0,115M\)