\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ n_{HCl}=\dfrac{36,5}{36,5}=1\left(mol\right)\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\a, V\text{ì}:\dfrac{0,1}{1}< \dfrac{1}{2}\Rightarrow HCl\text{dư}\\ n_{HCl\left(d\text{ư}\right)}=1-0,1.2=0,8\left(mol\right)\\ m_{HCl\left(d\text{ư}\right)}=0,8.36,5=29,2\left(g\right)\\ b,n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\\ m_{ZnCl_2}=136.0,1=13,6\left(g\right)\)