nAl = 4.05/27 = 0.15 (mol)
nH2SO4 = 400*7.35%=29.4 (g)
nH2SO4 = 0.3 (mol)
2Al + 3H2SO4 => Al2(SO4)3 + 3H2
2.............3
0.15........0.3
Lập tỉ lệ : 0.15/2 < 0.3/3
=> H2SO4 dư
mAl2(SO4)3 = 0.075*342 = 25.65 (g)
VH2 = 0.225*22.4 = 5.04 (l)
mdd sau phản ứng = 4.05 + 400 - 0.225*2 = 403.6 (g)
C%Al2(SO4)3 = 25.65/403.6 * 100% = 6.35%
C%H2SO4(dư) = (0.3-0.225)*98/403.6 * 100% = 1.82%
a) nAl= 4,05/27= 0,15(mol)
nH2SO4= (400.7,35%)/98=0,3(mol)
PTHH: 2Al +3 H2SO4 -> Al2(SO4)3 + 3 H2
Ta có: 0,15/2 < 0,3/3
=> Al hết, H2SO4 dư, tính theo nAl
nAl2(SO4)3= 0,15/2=0,075(mol)
=>m(muối)=mAl2(SO4)3=0,075.342=25,65(g)
b) nH2=nH2SO4(p.ứ)=3/2. 0,15= 0,225(mol)
V(H2,đktc)=0,225.22,4=5,04(l)
c) mH2SO4(dư)= (0,3-0,225).98=7,35(g)
mddsau= 4,05+400 - 0,225.2=403,6(g)
=>C%ddAl2(SO4)3= (25,65/403,6).100=6,355%
C%ddH2SO4(dư)= (7,35/403,6).100=1,821%