\(a,\text{Hiện tượng: Xuất hiện kết tủa màu nâu đỏ và màu dd }FeCl_3\text{ nhạt dần}\\ b,\left\{{}\begin{matrix}m_{FeCl_3}=\dfrac{32,5\cdot20\%}{100\%}=6,5\left(g\right)\\m_{KOH}=\dfrac{13,44\cdot25\%}{100\%}=3,36\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}n_{FeCl_3}=\dfrac{6,5}{162,5}=0,04\left(mol\right)\\n_{KOH}=\dfrac{3,36}{56}=0,06\left(mol\right)\end{matrix}\right.\\ PTHH:FeCl_3+3KOH\rightarrow Fe\left(OH\right)_3\downarrow+3KCl\\ \text{Vì }\dfrac{n_{FeCl_3}}{1}>\dfrac{n_{KOH}}{3}\text{ nên sau phản ứng }FeCl_3\text{ dư}\)
\(\Rightarrow n_{Fe\left(OH\right)_3}=\dfrac{1}{3}n_{KOH}=0,02\left(mol\right)\\ \Rightarrow m_{Fe\left(OH\right)_3}=0,02\cdot107=2,14\left(g\right)\\ n_{KOH}=n_{KCl}=0,06\left(mol\right)\\ \Rightarrow m_{CT_{KCl}}=0,06\cdot74,5=4,47\left(g\right)\\ m_{dd_{KCl}}=32,5+13,44-2,14=43,8\left(g\right)\\ \Rightarrow C\%_{KCl}=\dfrac{4,47}{43,8}\cdot100\%\approx10,21\%\)
