- Phần 1: \(n_{H_2}=\dfrac{1,344}{22,4}=0,06\left(mol\right)\)
Gọi \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\left(a,b>0\right)\)
PTHH:
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
a--------------------------->1,5a
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
b--------------------------->b
\(\Rightarrow1,5a+b=0,06\left(1\right)\)
- Phần 2: Đặt hệ số tỉ lệ \(\dfrac{P_2}{P_1}=k\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Al}=ak\left(mol\right)\\n_{Fe}=bk\left(mol\right)\end{matrix}\right.\Rightarrow ak+bk=0,15\left(2\right)\)
\(n_{H_2}=\dfrac{2,016}{22,4}=0,09\left(mol\right)\)
PTHH: \(2Al+2KOH+2H_2O\rightarrow2KAlO_2+3H_2\)
0,06<----------------------------------------0,09
\(\Rightarrow ak=0,06\left(3\right)\)
Từ \(\left(1\right),\left(2\right),\left(3\right)\Rightarrow\left\{{}\begin{matrix}a=0,02\\b=0,03\\k=3\end{matrix}\right.\)
\(\Rightarrow m=\left(0,02.27+0,03.56\right)\left(3+1\right)=8,88\left(g\right)\)