a. FeCl3 + 3NaOH --> Fe(OH)3 + 3NaCl;
0,1 ------------0,3-----------0,1-----------0,3
b. Ta có; nFeCl3=\(\dfrac{97,5\cdot25}{100\cdot162,5}=0,15\left(mol\right)\)
nNaOH= 0,3*1= 0,3 (mol)
Xét tỉ lệ:
\(\dfrac{nFeCl3}{nFeCl3pt}=\dfrac{0,15}{1}>\dfrac{nNaOH}{nNaOHpt}=\dfrac{0,3}{3}\)
=> FeCl3 dư. sản phẩm tính theo số mol NaOH.
nFe(OH)3= 0,1 (mol)=> mFe(OH)3= 0,1* 107=10,7 (g)
c. ta có: nNaCl= 0,3 (mol)=> mNaCl= 0,3*58,5=17,55(g)
nFeCl3 dư= 0,15-0,1=0,05(mol)=> mFeCl3=0,05*162,5=8,125(g)
mddNaOH=1,21*300=363 (g)
=> mdd sau pư= 97,5+363-10,7= 449,8(g)
C% NaCl=\(\dfrac{17,55\cdot100}{449,8}=3,9\%\)
C%FeCl3=\(\dfrac{8,125\cdot100}{449,8}=1,8\%\)