\(a.\)
\(H_2SO_4\rightarrow2H^++SO_4^{2-}\)
\(pH=-log\left[H^+\right]=3\)
\(\Leftrightarrow\left[H^+\right]=10^{-3}\left(M\right)\)
\(\left[SO_4^{2-}\right]=10^{-3}\left(M\right)\)
\(b.\)
\(Ca\left(OH\right)_2\rightarrow Ca^{2+}+2OH^-\)
\(pH=14+log\left[OH^-\right]=13\)
\(\Leftrightarrow\left[OH^-\right]=0.1\left(M\right)\)
\(\left[Ca^{2+}\right]=\dfrac{0.1}{2}=0.05\left(M\right)\)
\(\)