\(n_{Fe}=\dfrac{16,8}{56}=0,3(mol)\\ a,2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\\ 3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ b,n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2(mol)\\ \Rightarrow V_{O_2}=0,2.22,4=4,48(l)\\ n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{15}(mol)\\ \Rightarrow m_{KClO_3}=\dfrac{2}{15}.122,5\approx 16,33(g)\)