\(\overrightarrow{MB}=-2\overrightarrow{MC}\Leftrightarrow\overrightarrow{MB}=-2\left(\overrightarrow{MB}+\overrightarrow{BC}\right)\)
\(\Rightarrow3\overrightarrow{MB}=-2\overrightarrow{BC}\Rightarrow\overrightarrow{BM}=\frac{2}{3}\overrightarrow{BC}=\frac{2}{3}\left(\overrightarrow{BA}+\overrightarrow{AC}\right)=-\frac{2}{3}\overrightarrow{AB}+\frac{2}{3}\overrightarrow{AC}\)
\(\overrightarrow{AM}=\overrightarrow{AB}+\overrightarrow{BM}=\overrightarrow{AB}-\frac{2}{3}\overrightarrow{AB}+\frac{2}{3}\overrightarrow{AC}=\frac{1}{3}\overrightarrow{AB}+\frac{2}{3}\overrightarrow{AC}\)
\(\Rightarrow\left\{{}\begin{matrix}m=\frac{1}{3}\\n=\frac{2}{3}\end{matrix}\right.\) \(\Rightarrow mn=\frac{2}{9}\)