a) \(n_{khí}=n_{H_2}=\frac{6,72}{22,4}=0,3\left(mol\right)\)
Theo đề, ta có PTHH:
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(0,2--------->0,3\)
Theo phương trình: \(n_{Al}=\frac{2}{3}n_{H_2}=\frac{2}{3}.0,3=0,2\left(mol\right)\)
\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\Rightarrow\%m_{Al}=\frac{5,4}{8,6}.100\%=62,79\%\)
\(\Rightarrow\%m_{Cu}=100\%-62,79\%=37,21\%\)
b) \(m_{Cu}=8,6-5,4=3,2\left(g\right)\Rightarrow n_{Cu}=\frac{3,2}{64}=0,05\left(mol\right)\)
Theo đề, ta có PTHH:
\(2Al+6H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3SO_2+6H_2O\)
\(0,2------->0,1\)
\(Cu+2H_2SO_4\rightarrow CuSO_4+SO_2+2H_2O\)
\(0,05------>0,05\)
mmuối \(=m_{Al_2\left(SO_4\right)_3}+m_{CuSO_4}\\ =\frac{1}{2}.n_{Al}.342+n_{Cu}.160=\frac{1}{2}.0,2.342+0,05.160=42,2\left(g\right)\)
Vì: Cu không tác dụng với H2SO4 nên:
VH2 thoát ra là do Al
nH2= 0.3 (mol)
2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
nAl= 0.2 (mol)
mAl= 5.4g
mCu= 8.6-5.4=3.2g
%Al= 62.79%
%Cu= 37.21%
nCu= 0.05 (mol)
2Al + 6H2SO4 --> Al2(SO4)3 + 3SO2 + 6H2O
Cu + 2H2SO4 --> CuSO4 + SO2 + H2O
nAl2(SO4)= 0.1 (mol)
nCuSO4= 0.05 (mol)
mM= mAl2(SO4)3 + mCuSO4= 0.1*324 + 0.05*160=42.2g