\(n_{KMnO_4}=\dfrac{15.8}{158}=0.1\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(n_{O_2}=\dfrac{0.1}{2}=0.05\left(mol\right)\)
\(V_{O_2}=0.05\cdot22.4=1.12\left(l\right)\)
\(b.\)
\(n_P=\dfrac{6.2}{31}=0.2\left(mol\right)\)
\(4P+5O_2\underrightarrow{t^0}2P_2O_5\)
\(4.........5\)
\(0.2........0.05\)
\(LTL:\dfrac{0.2}{4}>\dfrac{0.05}{5}\Rightarrow Pdư\)
\(m_{P\left(dư\right)}=\left(0.2-0.04\right)\cdot31=4.96\left(g\right)\)
PTHH:2KMnO4--- K2MnO4+MnO2 +O2
ADCT nKmno4=15,8/158=0,1 mol
a, theo pt có nO2/nKmno4= 1/2
nO2=0,05 mol
ADCT V=n*22,4
VO2=0,05*22,4 =1,12 l
b, PTHH: 5O2+4P---2P2O5
ADCTnP=6,2/31=0,2 mol
Theo pt
nO2/5=0,01 bé hơn nP/4=0,05
P dư
theo pt nP(pư)/nO2=4/5
nP(p/ư)=0,04 mol
nP(dư)=0,05-0,04 =0,01 mol
ADCT:m=n*M
mP(dư)=0,01*31=0,31g