BaCl2 + H2SO4 ➜ BaSO4↓ + 2HCl
\(n_{BaCl_2}=0,3\times1=0,3\left(mol\right)\)
\(n_{H_2SO_4}=0,5\times1,5=0,75\left(mol\right)\)
Theo PT: \(n_{BaCl_2}=n_{H_2SO_4}\)
Theo bài: \(n_{BaCl_2}=\dfrac{2}{5}n_{H_2SO_4}\)
Vì \(\dfrac{2}{5}< 1\) ⇒ dd BaCl2 hết, dd H2SO4 dư
a) Theo PT: \(n_{BaSO_4}=n_{BaCl_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{BaSO_4}=0,3\times233=69,9\left(g\right)\)
b) Dung dịch thu được gồm: H2SO4 dư và HCl
Theo PT: \(n_{H_2SO_4}pư=n_{BaCl_2}=0,3\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}dư=0,75-0,3=0,45\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{BaCl_2}=2\times0,3=0,6\left(mol\right)\)
\(\Sigma m_{dd}=0,3+0,5=0,8\left(l\right)\)
\(C_{M_{H_2SO_4}}dư=\dfrac{0,45}{0,8}=0,5625\left(M\right)\)
\(C_{M_{HCl}}=\dfrac{0,6}{0,8}=0,75\left(M\right)\)
