a, PT: \(2Cu+O_2\underrightarrow{t^o}2CuO\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Gọi: \(\left\{{}\begin{matrix}n_{Cu}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\\n_{Al}=z\left(mol\right)\end{matrix}\right.\) ⇒ 64x + 56y + 27z = 40,4 (1)
Theo PT: \(\left\{{}\begin{matrix}n_{CuO}=n_{Cu}=x\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{3}y\left(mol\right)\\n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}z\left(mol\right)\end{matrix}\right.\)
⇒ 80x + 232.1/3x + 102.1/2z = 59,6 (2)
- Chất rắn A gồm: Cu, Fe và Al3O3.
⇒ 64x + 56y + 102.1/2z = 50 (3)
Từ (1), (2) và (3) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,3\left(mol\right)\\z=0,4\left(mol\right)\end{matrix}\right.\)
⇒ mCu = 0,2.64 = 12,8 (g)
mFe = 0,3.56 = 16,8 (g)
mAl = 0,4.27 = 10,8 (g)
b, Theo PT: \(n_{H_2}=n_{Cu}+\dfrac{4}{3}n_{Fe}=0,6\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,6.22,4=13,44\left(l\right)\)