\(a)\)\(PTHH:\)
\(Zn+2HCl--->ZnCl_2+H_2\)\((1)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PTHH (1) \(n_{Zn}=0,2\left(mol\right)\)
Khi cho hỗn hợp trên qua H2SO4 đặc nóng thì
\(Zn\left(0,2\right)+2H_2SO_4\left(đ\right)-t^o->ZnSO_4+SO_2\left(0,2\right)+2H_2O\)\(\left(2\right)\)
\(Cu\left(0,1\right)+2H_2SO_4\left(đ\right)-t^o->CuSO_4+SO_2\left(0,1\right)+2H_2O\)\(\left(3\right)\)
\(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PTHH (2) và (3) \(n_{Cu}=0,1\left(mol\right)\)
\(\Rightarrow\%m_{Zn}=\dfrac{0,2.65.100}{0,2.65+0,1.64}=67,01\%\)
\(\Rightarrow\%m_{Cu}=32,99\%\)