Gọi \(m_{HCl}=x\left(g\right)\)
=> \(m_{H_2SO_4}=x\left(g\right)\)
\(n_{CaCO_3}=\frac{25}{100}=0,25\left(g\right)\)
\(n_{Al}=\frac{a}{27}\left(mol\right)\)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
_______0,25------------------------------->0,25_________(mol)
=> mA (sau pư) = x + 25 - 0,25.44 = x + 14 (g)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
_______\(\frac{a}{27}\)-------------------------------------->\(\frac{a}{18}\)____(mol)
=> mB (sau pư) = x + a - \(2.\frac{a}{18}\) = x + \(\frac{8}{9}a\) (mol)
Do sau pư, cân thăng bằng
=> \(x+14=x+\frac{8}{9}a\)
=> a = 15,75 (g)
Ta có pthh :
CaCO3+ 2HCl---> CaCl2 + H2O + CO2 ( 1)
(0,25) (0,25)
2Al + 3H2SO4---->Al2(SO4)3 + 3H2 (2)
( \(\frac{m}{27}\) ) ( \(\frac{3.m}{2.27}\))
nCaCO3 =\(\frac{25}{100}\) = 0,25 mol ; nAl =\(\frac{m}{27}\)mol
Đặt mddHCl =mdd H2SO4= a g
m dd trong cốc A sau pư = 25 + a - 0,25.44 =(14 +a )g
mdd trong cốc B sau pư = m + a - \(\frac{3.m}{2.27}\) . 2
= ( m + a -\(\frac{m}{9}\)) g
Vì sau khi p.ư cân thăng bằng => 14 +a = m + a -\(\frac{m}{9}\)
<=> 14 = m - \(\frac{m}{9}\)
===> m = 15,75