a, \(n_{NaOH}=0,2.0,3=0,06\left(mol\right)\)
\(m_{MgCl_2}=400.30\%=120\left(g\right)\Rightarrow n_{MgCl_2}=\dfrac{120}{95}=\dfrac{24}{19}\left(mol\right)\)
PT: \(2NaOH+MgCl_2\rightarrow Mg\left(OH\right)_2+2NaCl\)
Xét tỉ lệ: \(\dfrac{0,06}{2}< \dfrac{\dfrac{24}{19}}{1}\), ta được MgCl2 dư.
Theo PT: \(n_{MgCl_2\left(pư\right)}=\dfrac{1}{2}n_{NaOH}=0,03\left(mol\right)\Rightarrow n_{MgCl_2\left(dư\right)}=\dfrac{24}{19}-0,03=\dfrac{2343}{1900}\left(mol\right)\)
\(\Rightarrow m_{MgCl_2\left(dư\right)}=\dfrac{2343}{1900}.95=117,15\left(g\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{NaCl}=n_{NaOH}=0,06\left(mol\right)\\n_{Mg\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=0,03\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{NaCl}=0,06.58,5=3,51\left(g\right)\\m_{Mg\left(OH\right)_2}=0,03.58=1,74\left(g\right)\end{matrix}\right.\)