Na2O + H2O → 2NaOH (1)
\(n_{Na_2O}=\frac{15,5}{62}=0,25\left(mol\right)\)
a) Theo PT1: \(n_{NaOH}=2n_{Na_2O}=2\times0,25=0,5\left(mol\right)\)
\(\Rightarrow C_{M_{NaOH}}=\frac{0,5}{0,5}=1\left(M\right)\)
b) 2NaOH + H2SO4 → Na2SO4 + 2H2O (2)
Theo pT2: \(n_{H_2SO_4}=\frac{1}{2}n_{NaOH}=\frac{1}{2}\times0,5=0,25\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,25\times98=24,5\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\frac{24,5}{20\%}=122,5\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\frac{122,5}{1,14}=107,46\left(ml\right)\)
c) Theo PT: \(n_{Na_2SO_4}=n_{H_2SO_4}=0,25\left(mol\right)\)
\(\Rightarrow C_{M_{Na_2SO_4}}=\frac{0,25}{0,10746}=2,33\left(M\right)\)
a. nNa2O=15,5/62=0,25 mol
Na2O+ 2H2O -->2NaOH +H2O
0,25mol --> 0,5mol
nNaOH=0,25.2=0,5mol
CM (NaOH)=n/V=0,5/0,5=1 (M)
b. 2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,5mol --> 0,25mol
theo phương trình: nH2SO4=0,25mol
mH2SO4=0,25.98=24,5 g
mddH2SO4=(24,5.100)/20 =122,5 g
Áp dụng CT m=D.V => V=m/D= 122,5/1,14=107,5 (ml) =0,1L
c). dd sau pư trung hòa là Na2SO4 :
CM = n/V=0,25/V
với V sau = VNaOH + VH2SO4=0,5+ 0,1=0,6
=> CM= 0,25/06= 0,42M