PTPU:
\(Fe+H_2SO_4->FeSO_4+H_2\uparrow\)
a a a
\(FeO+H_2SO_4->FeSO_4+H_2O\)
b b
\(FeCO_3+H_2SO_4->FeSO_4+CO_2\uparrow+H_2O\)
c c c
\(Mg+H_2SO_4->MgSO_4+H_2\uparrow\)
x x x
\(MgO+H_2SO_4->MgSO_4+H_2O\)
y y
\(MgCO_3+H_2SO_4->MgSO_4+CO_2\uparrow+H_2O\)
z z z
Ta có: \(n_Y=\dfrac{8,6765}{24,79}=0,35\left(mol\right)\) \(=>\left(a+x\right)+\left(c+z\right)=0,35\) (1)
\(d_{\dfrac{Y}{He}}=\dfrac{\overline{M}_Y}{M_{He}}=6,5\) \(=>\overline{M}_Y=6,5.4=26\)
\(=>m_Y=n.M=0,35.26=9,1\left(g\right)\) \(\Leftrightarrow2\left(a+x\right)+44\left(c+z\right)=9,1\) (2)
Từ (1),(2) \(=>\left\{{}\begin{matrix}a+x=0,15\\c+z=0,2\end{matrix}\right.\)
Ta có: \(m_X=m_{Fe}+m_{FeO}+m_{FeCO_3}+m_{Mg}+m_{MgO}+m_{MgCO_3}=30,8\)
\(=>56a+72b+116c+24x+40y+84z=30,8\)
\(72\left(a+b+c\right)+40\left(x+y+z\right)-16a+44c-16x+44z=30,8\)
\(72\left(a+b+c\right)+40\left(x+y+z\right)-16\left(a+x\right)+44\left(c+z\right)=30,8\)
\(72\left(a+b+c\right)+40\left(x+y+z\right)-16.0,15+44.0,2=30,8\)
\(72\left(a+b+c\right)+40\left(x+y+z\right)=24,4\) (3)
Ta lại có:\(m_Z=m_{FeSO_4}+m_{MgSO_4}=60,4\)
\(=>152\left(a+b+c\right)+120\left(x+y+z\right)=60,4\) (4)
Từ (3), (4) \(=>\left\{{}\begin{matrix}a+b+c=0,2\\x+y+z=0,25\end{matrix}\right.\)
Khối lượng MgSO4 trong Z là:
\(m_{MgSO_4}=120.0,25=30\left(g\right)\)