a) 2KOH +H2SO4 --> K2SO4 +2H2O(1)
2NaOH +H2SO4 --> Na2SO4 +2H2O (2)
nH2SO4=\(\dfrac{400.24,5}{100.98}=1\left(mol\right)\)
nKOH=\(\dfrac{200.28}{100.56}=1\left(mol\right)\)
lập tỉ lệ :
\(\dfrac{1}{1}>\dfrac{1}{2}\)=> H2SO4 dư , KOH hết => bài toán tính theo KOH
theo (1) : nH2SO4(1)=1/2nKOH=0,5(mol)
=> nH2SO4(2)=0,5(mol)
theo(2) : nNaOH=2nH2SO4(2)=1(mol)
=>mddNaOH=\(\dfrac{1.40.100}{10}=400\left(g\right)\)
b)theo (1) : nK2SO4=1/2nKOH=0,5(mol)
=>mK2SO4=87(g)
theo(2) : nNa2SO4=nH2SO4(2)=0,5(mol)
=>mNa2SO4=71(g)
mddsau pư=200+400+400=1000(g)
=> C%ddK2SO4=\(\dfrac{87}{1000}.100=8,7\left(\%\right)\)
C%ddNa2SO4=\(\dfrac{71}{1000}.100=7,1\left(\%\right)\)