nHCl=0,02 mol, nH2SO4=0.0025mol
=>nH+ =0,025 mol
Sau pứ pH=12=> OH- dư =>[OH-]=10-14:10-12=0,01M
=>nOH-=0,01*0,5=0,005M
=>nOH- cần= nH+ + nOH- dư=0,005+0,025=0,03(mol)
=>nBa(OH)2=nOH-/2=0,015mol
=>CBa(OH)2=0,015/0,25=0,06M=> x=0,06
dễ thấy nBa2+ >nSO42-
=>nBaSO4=nSO42-=0,0025mol
=>mBaSO4↓=0,0025*233=0,5825(g)