PTHH: \(Cu+2AgNO_3\rightarrow Cu\left(NO_3\right)_2+2Ag\)
x__________________x_______2x (mol)
Giả sử lượng Bạc bám hết vào thanh đồng
Ta có: \(3-64x+108\cdot2x=4,21\) \(\Rightarrow x\approx0,008\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Cu\left(p/ứ\right)}=n_{Cu\left(NO_3\right)_2}=0,008\left(mol\right)\\n_{Ag}=0,016\left(mol\right)\\\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Cu\left(p/ứ\right)}=0,008\cdot64=0,512\left(g\right)\\m_{Ag}=0,016\cdot108=1,728\left(g\right)\\m_{Cu\left(dư\right)}=2,488\left(g\right)\\m_{Cu\left(NO_3\right)_2}=0,008\cdot188=1,504\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Cu\left(ban.đầu\right)}+m_{ddAgNO_3}-m_{Ag}-m_{Cu\left(dư\right)}=228,784\left(g\right)\)
\(\Rightarrow C\%_{Cu\left(NO_3\right)_2}=\dfrac{1,504}{228,784}\cdot100\%\approx0,66\%\)