Gọi CTHH là RO
PTHH: RO + H2SO4 → RSO4 + H2O
Gọi \(n_{RO}=x\left(mol\right)\)
\(\Rightarrow m_{RO}=x\times\left(M_R+16\right)=xM_R+16x\left(g\right)\)
Theo PT: \(n_{H_2SO_4}=n_{RO}=x\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=98x\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\frac{98x}{24,5\%}=400x\left(g\right)\)
Ta có: \(m_{dd}saupư=m_{RO}+m_{ddH_2SO_4}=xM_R+16x+400x=xM_R+416x\left(g\right)\)
Theo PT: \(n_{RSO_4}=n_{RO}=x\left(mol\right)\)
\(\Rightarrow m_{RSO_4}=x\times\left(M_R+96\right)=xM_R+96x\left(g\right)\)
Ta có: \(C\%_{RSO_4}=\frac{xM_R+96x}{xM_R+416x}\times100\%=33,33\%\)
\(\Rightarrow\frac{M_R+96}{M_R+416}=0,3333\)
\(\Rightarrow M_R=64\left(đvC\right)\)
Vậy R là đồng Cu
Vật CTHH là CuO