a)
nMg=8,4/24=0,35(mol)
Bảo toàn nguyên tố Mg:
nMg(NO3)2=nMg=0,35(mol)
mMg(NO3)2=0,35.148=51,8(g)<55,8
→ Tạo muối NH4NO3
nNH4NO3=(55,8−51,8)/80=0,05(mol)
Bảo toàn electron:
2nMg=3nNO+8nNH4NO3
→2.0,35=3nNO+8.0,05
→nNO=0,1(mol)
VNO=0,1.22,4=2,24(l)
b)
nHNO3=10nNH4NO3+4nNO
=10.0,05+4.0,1=0,9(mol)
mdd HNO3=0,9.63/12,6%=450(g)
mdd spu=8,4+450−0,1.30=455,4(g)
C%Mg(NO3)2=51,8/455,4.100%=11,37%
C%NH4NO3=(55,8−51,8).100%/455,4=0,88%