2Al + 6HCl -> 2AlCl3 + 3H2 (1)
Fe + 2HCl -> FeCl2 -> H2 (2)
nH2=0,135(mol)
mAl,Fe=6-1,86=5,865(g)
Đặt nAl=a(mol)
nFe=b(mol)
Ta có hệ:
\(\left\{{}\begin{matrix}27a+56b=5,865\\1,5a+b=0,135\end{matrix}\right.\)
=>a=0,03;b=0,09
mAl=0,03.27=0,81(g)
Tự tính %m
b;
ta có:
nHCl=2nH2=0,27(mol)
V dd HCl=\(\dfrac{0,27}{2}=0,135\left(lt\right)\)
\(2Al\left(a\right)+6HCl\left(3a\right)\rightarrow2AlCl_3+3H_2\left(1,5a\right)\)
\(Fe\left(b\right)+2HCl\left(2b\right)\rightarrow FeCl_2+H_2\left(b\right)\)
\(m_{Al,Fe}=6-1,86=4,14\left(g\right)\Rightarrow27a+56b=4,14\left(II\right)\)
\(n_{H_2}=0,135\left(mol\right)\Rightarrow1,5a+b=0,135\left(I\right)\)
Từ (I,II) => a=0,06; b = 0,045
\(\Rightarrow\%m\)
\(V_{ddHHCl}=\dfrac{3.0,06+2.0,045}{2}=0,135M\)