a) Na2S+2HCl---->2NaCl+H2S
b) n Na2S=\(\frac{15,6}{78}=0,2\left(mol\right)\)
n HCl=0,3.2=0,6(mol)
---->HCl dư
Theo pthh
n H2S= n Na2S=0,2(mol)
V H2S=0,2.22,4=4,48(l)
c) dd sau pư là NaCl và HCl dư
n HCl dư=0,6-0,4=0,2(mol)
m ddHCl=300.1,15=345(g)
m dd sau pư=345+15,6=360,6(g)
C% HCl dư=\(\frac{0,2.36,5}{360,6}.100\%=2,02\%\)
n NaCl= n Na2S=0,2(mol)
C% NaCl=\(\frac{0,2.58,5}{360,6}.100\%=3,24\%\)
\(\text{a, Na2S + 2HCl ---> 2NaCl + H2S}\)
\(\text{b, n Na2S = 0,2 mol, n HCl = 0,6 mol }\)
Xét: (nNa2S ) < (n HCl/2)
---> Na2S hết, HCl dư, số mol H2S tính theo Na2S.
n H2S = n Na2S = 0,2 MOL
---> V H2S = 4,48 lít
\(\text{c, mdd HCl = 300.1,15 = 345g}\)
\(\text{m dd sau pứ = 15,6 + 345 - 0,2.34}\)
= 353,8g
n NaCl =n HCl pứ = 2. n Na2S = 0,4 mol
n HCl dư = 0,6 - 0,4 = 0,2 mol
\(\text{C%(NaCl) = 0,4. 58,5÷ 353,8.100% =6,6%}\)
\(\text{C%(HCl dư) = 0,2.36,5÷353,8.100%=2,06% }\)