a,\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,1 0,2 0,1 0,1
PTHH: Fe2O3 + 6HCl → 2FeCl3 + 3H2O
Mol: 0,05 0,3 0,1
\(m_{Fe}=0,1.56=5,6\left(g\right);m_{Fe_2O_3}=13,6-5,6=8\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
b,\(m_{HCl}=\left(0,2+0,3\right).98=49\left(g\right)\)
\(m_{ddHCl}=\dfrac{49.100}{10}=490\left(g\right)\)
c,\(m_{ddX}=13,6+490-0,1.2=503,4\left(g\right)\)
d,\(C\%_{FeCl_2}=\dfrac{0,1.127.100\%}{503,4}=2,52\%\)
\(C\%_{FeCl_3}=\dfrac{0,05.162,5.100\%}{503,4}=1,614\%\)
\(a.Fe+2HCl\rightarrow FeCl_2+H_2\left(1\right)\\ Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ \Rightarrow n_{Fe}=n_{H_2}=n_{FeCl_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Fe}=\dfrac{0,1.56}{13,6}.100\approx41,176\%\\ \Rightarrow\%m_{Fe_2O_3}\approx58,824\%\\ b.n_{Fe_2O_3}=\dfrac{13,6-0,1.56}{160}=0,05\left(mol\right)\\ n_{HCl}=2.n_{Fe}+6.n_{Fe_2O_3}=2.0,1+6.0,05=0,5\left(mol\right)\\ m_{ddHCl}=\dfrac{0,5.36,5.100}{10}=182,5\left(g\right)\)
\(c.m_{ddX}=m_{hh\left(Fe,Fe_2O_3\right)}+m_{ddHCl}-m_{H_2}=13,6+182,5-0,1.2=195,9\left(g\right)\\ d.n_{FeCl_3}=2.0,05=0,1\left(mol\right)\\ C\%_{ddFeCl_3}=\dfrac{0,1.162,5}{195,9}.100\approx8,295\%\\ C\%_{ddFeCl_2}=\dfrac{0,1.127}{195,9}.100\approx6,483\%\)
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1 0,1
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)
1 6 2 3
0,05 0,3 0,1
a) \(n_{Fe}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Fe}=01,.56=5,6\left(g\right)\)
\(m_{Fe2O3}=13,6-5,6=8\left(g\right)\)
0/0Fe = \(\dfrac{5,6.100}{13,6}=41,18\)0/0
0/0Fe2O3 = \(\dfrac{8.100}{13,6}=58,82\)0/0
b) \(n_{HCl\left(tổng\right)}=0,2+0,3=0,5\left(mol\right)\)
⇒ \(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{10}=182,5\left(g\right)\)
c) \(n_{FeCl2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
⇒ \(m_{FeCl2}=0,1.127=12,7\left(g\right)\)
\(n_{FeCl3}=\dfrac{0,3.2}{6}=0,1\left(mol\right)\)
⇒ \(m_{FeCl3}=0,1.162,5=16,25\left(g\right)\)
d) \(m_{ddspu}=13,6+182,5-\left(0,1.2\right)=195,9\left(g\right)\)
\(C_{FeCl2}=\dfrac{12,7.100}{195,9}=6,48\)0/0
\(C_{FeCl3}=\dfrac{16,25.100}{195,9}=8,3\)0/0
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