\(5SO_2+2KMnO_4+2H_2O\rightarrow2H_2SO_4+K_2SO_4+2MnSO_4\)
Ta có :
\(n_{KMnO4}=0,005\left(mol\right)\)
\(n_{SO2}=0,0125\left(mol\right);n_{H2SO4}=0,005\left(mol\right)\)
\(\Rightarrow n_{H^+}=0,01\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\frac{0,01}{0,1}=0,1M\)
\(p_H=-log\left[H^+\right]=1\)
\(\Rightarrow V=0,0125.22,4=0,28\left(l\right)\)