\(n_{O_2} = \dfrac{0,72}{22,4} = \dfrac{9}{280}(mol)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = \dfrac{9}{140}(mol)\\ m_{KMnO_4} = \dfrac{9}{140}.158 = 10,16(gam)\\ 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ n_{KClO_3} = \dfrac{2}{3}n_{O_2} = \dfrac{3}{140}(mol)\\ m_{KClO_3} = \dfrac{3}{140}.122,5 = 2,625(gam)\)
\(n_{O_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.6..............................................0.3\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(0.2..........................0.3\)
\(m_{KMnO_4}=0.6\cdot158=94.8\left(g\right)\)
\(m_{KClO_3}=0.2\cdot122.5=24.5\left(g\right)\)
\(n_{O_2}=\dfrac{V_{O_2\left(ĐKTC\right)}}{22,4}=\dfrac{0,72}{22,4}=0,03\left(mol\right)\)
- Điều chế O2 bằng KMnO4, ta có PTHH:
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
----2----------------------------------------------------1---
----0,06------------------------------------------------0,03---
\(m_{KMnO_4}=n_{KMnO_4}\cdot M_{KMnO_4}=0,06\cdot158=9,48\left(g\right)\)
- Điều chế O2 bằng KClO3, ta có PTHH:
\(2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\)
---2-------------------------------------3----
---0,02---------------------------------0,03----
\(m_{KClO_3}=n_{KClO_3}\cdot M_{KClO_3}=0,02\cdot122,5=2,45\left(g\right)\)
nO2=\(\dfrac{0,72}{32}\)=0,0225(mol)
PTHH 1 2KMnO4 →K2MnO4 +MnO2 +O2
Theo PTHH 1 ta có nKMnO4= 2 * 0,0225 = 0,045 (mol)
mKMnO4= 0,045 * 158= 7,11(g)
PTHH 2 : 2KClO3 → 2KCl + 3O2
Theo PTHH 2 ta có: nKClO3= \(\dfrac{2}{3}\) 0,0225 =0,015(mol)
m KClO3= 0,015 * 122,5 = 1,8375 (g)
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