Lời giải:
a) PTHH: 4Al + 3O2 =(nhiệt)=> 2Al2O3 (1)
Ta có: nAl2O3 = \(\frac{5,4}{27}=0,2\left(mol\right)\)
Theo phương trình, nAl2O3 = \(\frac{0,2\times2}{4}=0,1\left(mol\right)\)
=> Khối lượng Al2O3 thu được: mAl2O3 = \(0,1\cdot102=10,2\left(gam\right)\)
b) PTHH: 2KMnO4 =(nhiệt)=> K2MnO4 + MnO2 + O2 (2)
Theo PT(1), nO2 = \(\frac{0,2\times3}{4}=0,15\left(mol\right)\)
Theo PT(2), nKMnO4(lý thuyết) = \(0,15\cdot2=0,3\left(mol\right)\)
=> nKMnO4(thực tế) = \(0,3\div95\%=\frac{6}{19}\left(mol\right)\)
=> mKMnO4 = \(\frac{6}{19}\cdot158\approx49,9\left(gam\right)\)
a) \(n_{Al}=\frac{5.4}{27}=0.2\left(mol\right)\)
Phuong trinh hoa hoc:
\(4Al+3O_2\rightarrow2Al_2O_3\)
Theo phuong trinh hoa hoc:
\(n_{Al_2O_3}=\frac{1}{2}n_{Al}=\frac{1}{2}\cdot0.2=0.1\left(mol\right)\)
\(\rightarrow m_{Al_2O_3}=0.1\cdot102=10.2\left(g\right)\)
b) Theo phuong trinh hoa hoc:
\(n_{O_2}=\frac{3}{4}n_{Al}=\frac{3}{4}\cdot0.2=0.15\left(mol\right)\)
\(\rightarrow V_{O_2}=22.4\cdot0.15=3.36\left(l\right)\)
Ta co:
Vo2(theo pt) = Vo2(thu duoc) + 5%Vo2(hao hut)
= 3.36 + 0.168 = 3.528 (l)
\(\rightarrow n_{O_2\left(pt\right)}=\frac{3.528}{32}=0.11025\left(l\right)\)
Phuong trinh hoa hoc:
\(2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)
Theo pthh: \(n_{KMnO_4}=2n_{O_2}=2\cdot0.11025=0.2205\left(mol\right)\)
\(\rightarrow m_{KMnO_4}=0.2205\cdot158=34.839\left(g\right)\)