a, \(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)gdf
b, Gọi số mol KClO3 và KMnO4 lần lượt là x,y ( mol ) ( x,y > 0 )
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
x(mol)......................\(\dfrac{3}{2}x\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
y(mol)..............................................\(\dfrac{1}{2}y\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Tổng số mol O2 : \(\dfrac{3}{2}x+\dfrac{1}{2}y=0,05\left(1\right)\)
\(m_{KClO_3}=n.M=122,5x\left(g\right)\)
\(m_{KMnO_4}=n.M=158y\left(g\right)\)
\(\Rightarrow122,5x+158y=8,77\left(2\right)\)
Từ (1)(2) ,có :\(\left\{{}\begin{matrix}\dfrac{3}{2}x+\dfrac{1}{2}y=0,05\\122,5x+158y=8,77\end{matrix}\right.\) ( bấm máy tính là ra )
\(\Rightarrow\left\{{}\begin{matrix}x=0,02\\y=0,04\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{KClO_3}=122,5.x=122,5.0,02=2,45\left(g\right)\\m_{KMnO_4}=158y=158.0,04=6,32\left(g\right)\end{matrix}\right.\)
\(\%m_{KClO_3}=\dfrac{2,45}{8,77}.100\%=27\%\)
\(\%m_{KMnO_4}=\dfrac{6,32}{8,77}.100\%=73\%\)
nO2=1,12/22,4=0,05(mol)
2KClO3--->2KCl+3O2
x_______________3/2x
2KMnO4--->K2MnO4+MnO2+O2
y__________________________1/2y
Hệ pt:
\(\left\{{}\begin{matrix}122,5x+158y=8,77\\1,5x+0,5y=0,05\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,02\\y=0,04\end{matrix}\right.\)
=>mKClO3=0,02.122,5=2,45(g)
=>%mKClO3=2,45/8,77.100%~27,9%
=>%mKMnO4=100%-27,9%=72,1%
a) PTHH: 2KClO3 --to-> 2KCl + 3O2\(\uparrow\)
................a(mol).........................\(\dfrac{3}{2}a\)(mol)....
2KMnO4 --to--> MnO2+O2+K2MnO4
....b(mol)......................\(\dfrac{1}{2}b\)(mol)....
b) \(n_{O2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
- Gọi số mol của KClO3, KMnO4 lần lượt là a(mol), b(mol)
Từ đó ta có hệ;
\(\left\{{}\begin{matrix}122,5a+158b=8,77\\\dfrac{3}{2}a+\dfrac{1}{2}b=0,05\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,02\left(mol\right)\\b=0,04\left(mol\right)\end{matrix}\right.\)
\(\%KClO_3=\dfrac{0,02.122,5}{8,77}.100\%=27,94\%\)
\(\%KMnO_4=100\%-27,94\%=72,06\%\)
Câu c thì bn dựa vào câu b mà tính nhé