m(ZnCl2)= 170*12/100=20,4g
n(ZnCl2)= 0,15mol
n(Zn(OH)2)=0,1mol < n(ZnCl2) =0,15
=> ZnCl2 dư
2NaOH + ZnCl2-> 2NaCl+Zn(OH)2
Số mol NaOH=2n(Zn(OH)2)=0,2 MOL
m(NaOH)= 8(g)
m(ddnaoh)=8*100/10=80(g)
\(n_{ZnCl_2}=\dfrac{170\cdot12\%}{136}=0.15\left(mol\right)\)
\(n_{Zn\left(OH\right)_2}=\dfrac{9.9}{99}=0.1\left(mol\right)\)
\(ZnCl_2+2NaOH\rightarrow Zn\left(OH\right)_2+2NaCl\)
TH1 : Kết tủa không bị hòa tan.
\(n_{NaOH}=2n_{Zn\left(OH\right)_2}=2\cdot0.1=0.2\left(mol\right)\)
\(m_{dd_{NaOH}}=\dfrac{0.2\cdot40}{10\%}=80\left(g\right)\)
TH2 : Kết tủa bị hòa tan một phần.
\(ZnCl_2+2NaOH\rightarrow Zn\left(OH\right)_2+2NaCl\)
\(0.15............0.3...........0.15\)
\(2NaOH+Zn\left(OH\right)_2\rightarrow Na_2ZnO_2+2H_2O\)
\(2x...........x\)
\(n_{Zn\left(OH\right)_2}=0.15-x=0.1\left(mol\right)\)
\(\Rightarrow x=0.05\)
\(n_{NaOH}=0.3+2\cdot0.05=0.4\left(mol\right)\)
\(m_{dd_{NaOH}}=\dfrac{0.4\cdot40}{10\%}=160\left(g\right)\)
