Ta có: \(n_{Al}=\dfrac{8,64}{27}=0,32\left(mol\right)\)
\(Al:0,32\left(mol\right)+74,7\left(g\right)\left\{{}\begin{matrix}CuCl_2:x\\FeCl_3:0,18+y\end{matrix}\right.\) \(\rightarrow\) \(17,76\left(g\right)\left\{{}\begin{matrix}Cu:x\\Fe:y\end{matrix}\right.\) + \(\left\{{}\begin{matrix}AlCl_3\\FeCl_2\end{matrix}\right.\)
Theo ĐLBT KL, có: mAlCl3 + mFeCl2 = 8,64 + 74,7 - 17,76 = 65,58 (g)
BTNT Al, có: nAlCl3 = nAl = 0,32 (mol)
⇒ nFeCl2 = 0,18 (mol)
Có: 64x + 56y = 17,76 (1)
BT e, có: 2x + 3y + 0,18.1 = 0,32.3 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,12\left(mol\right)\\y=0,18\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\dfrac{n_{FeCl_3}}{n_{CuCl_2}}=\dfrac{0,18+0,18}{0,12}=\dfrac{3}{1}\)