PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
Bđ____0,05______0,2
Pư____0,05______0,1______0,05
Kt_____0_______0,1_______0,05
C/m sau pư: CaCO3 hết, HCl dư
\(n_{HCl}=0,2\left(mol\right)\)
\(m_{ddsaupư}=m_{CaCO_3}+m_{ddA}-m_{CO_2}=5+0,2.36,5+32,7-0,05.44=42,8\left(g\right)\)
\(m_{HCldư}=0,1.36,5=3,65\left(g\right)\)
\(\Rightarrow C\%ddHCl=\dfrac{3,65}{42,8}.100\%\approx8,5\%\)
\(C\%ddCaCl_2=\dfrac{0,05.111}{42,8}.100\%\approx12,97\%\)
nHCl= 4,48/22,4= 0,2(mol)
=> mHCl= 0,2.36,5= 7,3(g)
=> mddHCl= 32,7+7,3= 40(g)
PTHH: CaCO3 + 2 HCl -> CaCl2 + H2O + CO2
nCaCO3= 5/100= 0,05(mol)
Ta có: 0,2/2 > 0,05/1
=> HCl dư, CaCO3 hết, tính theo nCaCO3.
=> DD sau phản ứng gồm dd HCl (dư) và dd CaCl2
nCO2= nCaCl2= nCaCO3= 0,05 (mol)
nHCl(p.ứ)= 0,05.2= 0,1(mol)
=> nHCl(dư)= 0,2- 0,1= 0,1(mol)
=> mCaCl2= 111.0,05= 5,55(g)
mHCl(dư) = 0,1.36,5= 3,65(g)
mCO2= 0,05.44= 2,2(g)
mddsauphảnứng= 40+ 5 - 2,2= 42,8(g)
=> C%ddCaCl2= (5,55/42,8).100 \(\approx\) 12,967%
C%ddHCl(dư) = (3,65/42,8).100 \(\approx\)8,528%