MnO2+4HCl->MnCl2+H2O+Cl2
0,5---------2------0,5--------0,5---0,5
Cl2+2NaOH->NaClO+NaCl+H2O
0,5-----1--------0,5----------0,5------0,5
n MnO2 =\(\dfrac{43.5}{87}\)=0,5 mol
n NaOH=5.0,4=2 mol
=>NaOH dư :0,1 mol
=>CM NaCl= CM NaClO =\(\dfrac{1}{0,4}\)=2,5M
=>CM NaOH dư =1\(\dfrac{1}{0,4}\)=2,5M
b)
C%HCl =\(\dfrac{2.36,5}{250}100\)=29,2%
dùng dư 10%
=>C%HCl=29,2+10=39,2%